Preparation of metallic bismuth by reduction of bismuth formates in ethylene glycol medium

نویسندگان

چکیده

Nano -and microcrystalline bismuth metal powders consisting of spherical particles with a size 150-250 nm were obtained by reducing formates in an ethylene glycol medium. The phase composition and morphology the reaction products studied X-ray thermal analysis, differential scanning calorimetry, transmission electron microscopy. Using Uv-vis, it was shown that bismuth-ethylene complex is formed absorption maximum at 249 extinction coefficient 5.7×10 3 (L mol -1 cm ) solution chloric acid 23°C. concentration enhances to 0.018 g L medium gradual increase temperature 60°C mixture. Thermolysis glycolate Bi 2 (OCH CH O) accompanied formation metallic 190°C, which oxidized monoclinic modification oxide when increases air.

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ژورنال

عنوان ژورنال: MATEC web of conferences

سال: 2021

ISSN: ['2261-236X', '2274-7214']

DOI: https://doi.org/10.1051/matecconf/202134001014