Preparation of metallic bismuth by reduction of bismuth formates in ethylene glycol medium
نویسندگان
چکیده
Nano -and microcrystalline bismuth metal powders consisting of spherical particles with a size 150-250 nm were obtained by reducing formates in an ethylene glycol medium. The phase composition and morphology the reaction products studied X-ray thermal analysis, differential scanning calorimetry, transmission electron microscopy. Using Uv-vis, it was shown that bismuth-ethylene complex is formed absorption maximum at 249 extinction coefficient 5.7×10 3 (L mol -1 cm ) solution chloric acid 23°C. concentration enhances to 0.018 g L medium gradual increase temperature 60°C mixture. Thermolysis glycolate Bi 2 (OCH CH O) accompanied formation metallic 190°C, which oxidized monoclinic modification oxide when increases air.
منابع مشابه
Preparation and Characterization of Bismuth Sulfide (Bi2S3) Nanostructures by Ultrasonic Method
In the present work, Bi2S3 nanostructures have been synthesized with the aid of thioglycollic acid (TGA) a solvent, capping agent, and sulfide source in the presence of ultrasonic method. The as-synthesized products were characterized by X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDS), scanning electron microscope (SEM), and photoluminescence (PL) spectroscopy. The band gap ...
متن کاملUsing Taguchi Method to Optimize Recovery of Bismuth by Electrolysis
This paper presents a methodology, based on the taguchi parameter design approach, for the optimization of process parameters for bismuth recovery from aqueous solutions. The process parameters considered are [Bi3+], [NaCl], temperature, and cathodic current density. In addition, cell voltage and current efficiency as two responses have been considered. An orthogonal array L9, the signal-to-noi...
متن کاملstudy of cohesive devices in the textbook of english for the students of apsychology by rastegarpour
this study investigates the cohesive devices used in the textbook of english for the students of psychology. the research questions and hypotheses in the present study are based on what frequency and distribution of grammatical and lexical cohesive devices are. then, to answer the questions all grammatical and lexical cohesive devices in reading comprehension passages from 6 units of 21units th...
Nanoscale mechanisms for the reduction of heat transport in bismuth
HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: MATEC web of conferences
سال: 2021
ISSN: ['2261-236X', '2274-7214']
DOI: https://doi.org/10.1051/matecconf/202134001014